HOW DO SOLAR CELLS WORK?

Solar (or photovoltaic) cells convert the sun’s energy into electricity. Whether they’re adorning your calculator or orbiting our planet on satellites, they rely on the the photoelectric effect: the ability of matter to emit electrons when a light is shone on it.

Silicon is what is known as a semi-conductor, meaning that it shares some of the properties of metals and some of those of an electrical insulator, making it a key ingredient in solar cells. Let’s take a closer look at what happens when the sun shines onto a solar cell.

Sunlight is composed of miniscule particles called photons, which radiate from the sun. As these hit the silicon atoms of the solar cell, they transfer their energy to lose electrons, knocking them clean off the atoms. The photons could be compared to the white ball in a game of pool, which passes on its energy to the coloured balls it strikes.

Freeing up electrons is however only half the work of a solar cell: it then needs to herd these stray electrons into an electric current. This involves creating an electrical imbalance within the cell, which acts a bit like a slope down which the electrons will flow in the same direction.

Creating this imbalance is made possible by the internal organisation of silicon. Silicon atoms are arranged together in a tightly bound structure. By squeezing small quantities of other elements into this structure, two different types of silicon are created: n-type, which has spare electrons, and p-type, which is missing electrons, leaving ‘holes’ in their place.

When these two materials are placed side by side inside a solar cell, the n-type silicon’s spare electrons jump over to fill the gaps in the p-type silicon. This means that the n-type silicon becomes positively charged, and the p-type silicon is negatively charged, creating an electric field across the cell. Because silicon is a semi-conductor, it can act like an insulator, maintaining this imbalance.

As the photons smash the electrons off the silicon atoms, this field drives them along in an orderly manner, providing the electric current to power calculators, satellites and everything in between.

HISTORY OF SOLAR CELL

The photovoltaic effect was first experimentally demonstrated by French physicist A. E. Becquerel. In 1839, at age 19, experimenting in his father’s laboratory, he built the world’s first photovoltaic cell. Willoughby Smith first described the “Effect of Light on Selenium during the passage of an Electric Current" in an article that was published in the 20 February 1873 issue of Nature. However, it was not until 1883 that the first solid state photovoltaic cell was built, by Charles Fritts, who coated the semiconductor selenium with an extremely thin layer of gold to form the junctions. The device was only around 1% efficient. In 1888 Russian physicist Aleksandr Stotelov built the first photoelectric cell based on the outer photoelectric effect discovered by Heinrich Hertz earlier in 1887.

Albert Einstein explained the underlying mechanism of light instigated carrier excitation—the photoelectric effect—in 1905, for which he received the Nobel prize in Physics in 1921. Russell Ohlpatented the modern junction semiconductor solar cell in 1946, which was discovered while working on the series of advances that would lead to the transistor.

The first practical photovoltaic cell was developed in 1954 at Bell Laboratories by Daryl Chapin, Calvin Souther Fuller and Gerald Pearson. They used a diffused silicon p–n junction that reached 6% efficiency, compared to the selenium cells that found it difficult to reach 0.5%. Les Hoffman CEO of Hoffman Electronics Corporation had his Semiconductor Division pioneer the fabrication and mass production of solar cells. From 1954 to 1960 Hoffman improved the efficiency of Solar Cells from 2% to 14%. At first, cells were developed for toys and other minor uses, as the cost of the electricity they produced was very high; in relative terms, a cell that produced 1 watt of electrical power in bright sunlight cost about $250, comparing to $2 to $3 per watt for a coal plant.

Solar cells were brought from obscurity by the suggestion to add them, probably due to the successes made by Hoffman Electronics, to the Vanguard I satellite, launched in 1958. In the original plans, the satellite would be powered only by battery, and last a short time while this ran down. By adding cells to the outside of the body, the mission time could be extended with no major changes to the spacecraft or its power systems. In 1959 the United States launched Explorer 6. It featured large solar arrays resembling wings, which became a common feature in future satellites. These arrays consisted of 9600 Hoffman solar cells. There was some skepticism at first, but in practice the cells proved to be a huge success, and solar cells were quickly designed into many new satellites, notably Bell’s own Telstar.

INTRODUCING SOLAR ENERGY

Solar energy is the most readily available source of energy. It does not belong to anybody and is, therefore, free. It is also the most important of the non-conventional sources of energy because it is non-polluting and, therefore, helps in lessening the greenhouse effect.

Solar energy has been used since prehistoric times, but in a most primitive manner. Before 1970, some research and development was carried out in a few countries to exploit solar energy more efficiently, but most of this work remained mainly academic. After the dramatic rise in oil prices in the 1970s, several countries began to formulate extensive research and development programmes to exploit solar energy.

When we hang out our clothes to dry in the sun, we use the energy of the sun. In the same way, solar panels absorb the energy of the sun to provide heat for cooking and for heating water. Such systems are available in the market and are being used in homes and factories.

In the next few years it is expected that millions of households in the world will be using solar energy as the trends in USA and Japan show. In India too, the Indian Renewable Energy Development Agency and the Ministry of Non-Conventional Energy Sources are formulating a programme to have solar energy in more than a million households in the next few years. However, the people’s initiative is essential if the programme is to be successful.

India is one of the few countries with long days and plenty of sunshine, especially in the Thar desert region. This zone, having abundant solar energy available, is suitable for harnessing solar energy for a number of applications. In areas with similar intensity of solar radiation, solar energy could be easily harnessed. Solar thermal energy is being used in India for heating water for both industrial and domestic purposes. A 140 MW integrated solar power plant is to be set up in Jodhpur but the initial expense incurred is still very high.

Solar energy can also be used to meet our electricity requirements. Through Solar Photovoltaic (SPV) cells, solar radiation gets converted into DC electricity directly. This electricity can either be used as it is or can be stored in the battery. This stored electrical energy then can be used at night. SPV can be used for a number of applications such as:

a. domestic lighting 

b. street lighting 

c. village electrification 

d. water pumping 

e. desalination of salty water 

f. powering of remote telecommunication repeater stations  

I think the cost of energy will come down when we will make the transition to renewable energy - Algore